I'm in Love with the Villainess DVD Complete Edition English Dubbed

Rei Oohashi is a burned-out office worker by day but otome game heroine Rae Taylor by night. After her long workdays, Rei immerses herself in the world of her favorite dating sim, Revolution, as a student at Bauer Kingdom's prestigious Royal Academy. 
Instead of focusing on the male love interests, Rei obsesses over the romantic rival: the game's villainess, Claire François. One evening, however, Rei's exhaustion catches up with her and she passes away.

Episode titles:

• 1. Rushing Headlong into Life in Another World
• 2. A Maid's Job Is a Labor of Love
• 3. My Love Is a Series of Ups and Downs
• 4. When Monsters Attack, Unpreparedness Is the Greatest Enemy
• 5. The Knight Exam Is Packed with Drama
• 6. The Secret Reason Must Not Be Told to Anyone
• 7. What Makes or Breaks a School Fair Is the Cross-Dressing Cafe
• 8. The Swirling Currents Are All Machinations
• 9. My Master Will Never Change
• 10. My New Rival in Love Is a Perfect Superhuman
• 11. A Near-Miss in Love Is Certain Doom
• 12. The Villainess and I Are in Love